Search results for "Strong electrolyte"
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Nature of (C5Me5)2Mo2O5in water–methanol at pH 0–14. On the existence of (C5Me5)MoO2(OH) and (C5Me5)MoO2+: a stopped-flow kinetic analysis
2002
A stopped-flow analysis of compound Cp*2Mo2O5 (Cp* = η5-C5Me5) in 20% MeOH–H2O over the pH range 0–14 has provided the speciation of this molecule as well as the rate and mechanism of interconversion between the various species that are present in solution. The compound is a strong electrolyte in this solvent combination, producing the Cp*MoO2+ and Cp*MoO3− ions in equilibrium with a small amount of Cp*MoO2(OH), the latter attaining ca. 15% relative amount at pH 4. At low pH ( 6. The acid dissociation constant of Cp*MoO2(OH) has been measured directly (pK = 3.65 ± 0.02) while the pK for the protonation equilibrium leading to Cp*MoO3H2+ is estimated as 5. The prevalent pathway at high pH i…
Generalization of a finite-difference numerical method for the steady-state and transient solutions of the nernst—planck flux equations
1985
Abstract A generalization of the numerical method of Brumleve and Buck for the solution of Nernst—Planck equations when convective flux and electric current are involved has been developed. The simulation procedure was applied to a specific case: transport of strong electrolytes in a wide-pore membrane with simultaneous diffusion, convection and electric current. Good agreement was found between experimental data and computed results.